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A new approach to quantitatively assessing the effects of polymer additives

Fearon, Peter K and Phease, Tanya L and Billingham, Norman C and Bigger, Stephen W (2002) A new approach to quantitatively assessing the effects of polymer additives. Polymer, 43 (17). pp. 4611-4618. ISSN 0032-3861

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Abstract

A novel approach involving stability parameter mapping and stability vector analysis is developed for assessing the effect of an additive on polymer performance. The potential usefulness of the method is illustrated by applying it to (i) DSC oxidative induction time (OIt) data for medium-density polyethylene (MDPE) formulations made using two levels of carbon black and base-stabilized with Irgafos 168™ (tris-(2,4-di-tert-butylphenyl)-phosphite) and Irganox 1010™ pentaerythrityl-tetrakis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate), and (ii) chemiluminescence OIt data for low-density polyethylene (LDPE) containing 0.2% (w/w) of Chimassorb 944™ and 0.5% (w/w) or 1.0% (w/w) of dicumyl peroxide cross-linking agent and base-stabilized with 0.2% (w/w) of various commercial antioxidants. The proposed method is validated using data from a previous study on MDPE and is applied to a preliminary investigation of LDPE destabilization by dicumyl peroxide. The results suggest that a styrenated phenolic stabilizer blended with zinc dibutyldithiocarbamate and zinc stearate is an effective system for stabilizing LDPE in the presence of dicumyl peroxide.

Item Type: Article
Uncontrolled Keywords: polyethylene, thermooxidative stability, cross-linking agent
Subjects: RFCD Classification > 300000 Agricultural, Veterinary and Environmental Sciences
Faculty/School/Research Centre/Department > School of Biomedical and Health Sciences
Depositing User: Ms Phung T Tran
Date Deposited: 20 Oct 2008 22:13
Last Modified: 08 Oct 2013 01:54
URI: http://vuir.vu.edu.au/id/eprint/1099
DOI: 10.1016/S0032-3861(02)00295-1
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Citations in Scopus: 6 - View on Scopus

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